MSDS of Trioctyl amine

- Apr 04, 2018-

洛阳矿友贸易有限公司

MSDS:

KY005-EN

DATE:

6/20/2014

LUOYANG MINE FRIEND TRADING CO., LTD

 

 

MATERIAL SAFETY DATE SHEET

Section 1. Chemical Product and Company Identification

Chemical Name

Trioctyl amine

Product name

Trioctyl amine; TOA

Material Uses

It’s mainly used to   synthesis of cationic and amphoteric surfactants etc, which are used as fiber   detergents, fabric-softeninig agents. anticorrosice agents, flotation agents   of ore and emulsion agents of bitumen etc.

Manufacturer

LUOYANG MINE FRIEND TRADING CO.,LTD

Room513,   Building1,World Trade Center,258 Kaiyuan    Avenue,Luolong District,Luoyang,China

TEL:0086-379-61109972

FAX:0086-379-61109952

                                                                             

Section 2. Hazard identification

GHS HAZARD CLASSIFICATION:

PHYSICAL:

No classification.

HEALTH:

Skin   corrosion/irritation: Category 2 – H315: Causes skin irritation.

Serious eye damage/eye   irritation: Category 2 – H319: Causes serious eye

irritation.

STOT SE. Category 3-   H335: May cause respiratory irritation.

ENVIRONMENTAL:

Chronic hazards to the   aquatic environment: Category 4 – H413: May cause

long lasting harmful   effects to aquatic life. [Korea Occupational Safety & Health Agency,   June 2010.]

 

GHS LABEL ELEMENTS:

PICTOGRAM:


SIGNAL WORD:

Warning

HAZARD

STATEMENTS:

 

H315: Causes skin   irritation.

H319: Causes serious   eye irritation.

H335: May cause   respiratory irritation.

H413: May cause long   lasting harmful effects to aquatic life. [Korea

Occupational Safety   & Health Agency, June 2010.]

 

PRECAUTIONARY

STATEMENTS:

 

PREVENTION:

P261: Avoid breathing   dust/fume/gas/mist/vapors/spray.

P264: Wash hands and   face thoroughly after handling.

P271: Use only   outdoors or in a well-ventilated area.

P273: Avoid release to   the environment.

P280: Wear protective   gloves/protective clothing/eye protection/face

protection (refer to   Section 8 of this Safety Data Sheet).

RESPONSE:

P302 + P352: IF ON   SKIN: Wash with plenty of soap and water.

P304 + P340: IF   INHALED: Remove victim to fresh air and keep at rest in a

position comfortable   for breathing.

P305 + P351 + P338: IF   IN EYES: Rinse cautiously with water for several

minutes. Remove   contact lenses, if present and easy to do. Continue

rinsing.

P332 + P313: If skin   irritation occurs: Get medical advice/attention.

P312: Call a POISON   CENTER or doctor/physician if you feel unwell.

STORAGE:

P403+P233: Store in a   well-ventilated place. Keep container tightly closed.

P405: Store locked up.

DISPOSAL:

P501: Dispose of   contents / container in accordance with local regulations.

 

EC REGULATIONS:

CLASSIFICATION [REGULATION (EC) No. 1272/2008]:

Skin   corrosion/irritation: Category

2

H315: Causes skin   irritation.

Serious eye damage/eye   irritation:

Category 2

H319: Causes serious   eye irritation.

STOT SE: Category 3

H335: May cause   respiratory irritation.

Chronic hazards to the   aquatic

environment: Category   3

H413: May cause long   lasting harmful effects to aquatic life.

 

CLASSIFICATION [REGULATION 67/548/EEC; 1999/45/EC]:

– IRRITANT (Xi)

R36/37/38: Irritating   to eyes, respiratory system and skin.

– DANGEROUS FOR THE

ENVIRONMENT (N)

R53: May cause   long-term adverse effects in the aquatic

environment.

 

Section 3. Composition, Information on Ingredients

COMPONENTS

CAS No.

EINECS No.

Self / EC

Classification

Classification

Regulation (EC) No.   1272/2008

WT%

Trioctyl amine

1116-76-3

214-242-1

Xi; R36/37/38,

-N;R53

 

H315: Causes skin   irritation.

H319: Causes serious   eye

irritation.

H335: May cause   respiratory

irritation.

H413: May cause long   lasting

harmful effects to   aquatic life.

 

95.0

 

Water

7732-18-5

231-791-2

——

——

0.5

 

For the full text of the R-Phrases mentioned in this section, see Section 16.

For the full text of the H-Statements mentioned in this section, see Section 16.

                                                                                        

 

Section 4. First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the

upper and lower eyelids. Get medical aid.

Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while

removing contaminated clothing and shoes. Wash clothing before reuse.

Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Notes to Physician: Treat symptomatically and supportively. For methemoglobinemia,administer oxygen alone or with Methylene blue depending on the methemoglobinemia concentration in the blood.

Antidote: Methylene blue, alone or in combination with oxygen is indicated as a treatment in nitrite induced methemoglobinemia.

                                                                                       

Section 5. Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Vapors may form an explosive mixture with air. Containers may explode when heated.Combustible material; may burn but does not ignite readily. Runoff from fire control or dilution water may cause pollution.

Extinguishing Media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.

Flash Point: > 112 deg C (> 233.60 deg F)

Autoignition Temperature: 315 deg C ( 599.00 deg F)

Explosion Limits, Lower: Not available. Upper: Not available.

NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

 

incompatible substances.

 

Section 8. Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits

Chemical Name

ACGIH

NIOSH

OSHA - Final PELs

Trioctyl amine

none listed

none listed

none listed

OSHA Vacated PELs: Trioctyl amine: No OSHA Vacated PELs are listed for this chemical.

Personal Protective Equipment

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.

Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

                                                                                       

Section 9. Physical and Chemical Properties

Physical State: Liquid

Appearance: clear, colorless

Odor: None reported.

pH: Not available.

Vapor Pressure: Not available.

Vapor Density: 12.1

Evaporation Rate:Not available.

Viscosity: Not available.

Boiling Point: 365 - 367 deg C @ 760.00mm Hg

Freezing/Melting Point: Not available.

Decomposition Temperature: Not available.

Solubility: insoluble

Specific Gravity/Density:.8090g/cm3

Molecular Formula: C27H57N

Molecular Weight: 350.65

Flash Point: > 112 deg C (> 233.60 deg F)

Autoignition Temperature: 315 deg C ( 599.00 deg F)

Explosion Limits, Lower: Not available. Upper: Not available.

NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

 

Section 10. Stability and Reactivity

Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.

Conditions to Avoid: Incompatible materials, excess heat, strong oxidants.

Incompatibilities with Other Materials: Oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates.

Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Hazardous Polymerization: Has not been reported.

 

Section 11. Toxicological Information

Potential Health Effects

Eye: Causes eye irritation. May cause chemical conjunctivitis.

Skin: Causes skin irritation. May cause severe irritation and possible burns.

Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause

liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia,

cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and

death. May cause central nervous system depression.

Inhalation: Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis,

convulsions, tachycardia, dyspnea (labored breathing), and death. May cause liver and kidney

damage. May cause cardiac abnormalities. Can produce delayed pulmonary edema. Inhalation at

high concentrations may cause CNS depression and asphixiation.

Chronic: May cause liver and kidney damage. May cause methemoglobinemia, which is

characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath

shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate,

unconsciousness and possible death. Effects may be delayed.

RTECS#: No information found.

CAS# 1116-76-3

LD50/LC50: Not available.

Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.

Epidemiology: No information found.

Teratogenicity: No information found.

Reproductive Effects: No information found.

Neurotoxicity: No information available.

Mutagenicity: No information found.

Other Studies: No data available.

 

Section 12. Ecological Information

No information available.

Section 13. Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

Section 14. Transport Information

Land - Rail / Road

UN No.:

2735

(RID / ADR):

Name and Description:

AMINES, LIQUID,   CORROSIVE, N.O.S.

(Trioctyl   / Decyl amine)

Labelling:

8

UN Packing Group:

III

Class or Division:

8

Environment Hazards:

NO

Sea (IMO / IMDG):

 

UN No.:

2735

Name and Description:

AMINES, LIQUID,   CORROSIVE, N.O.S.

(Trioctyl   amine)

Labeling:

8

UN Packing Group:

III

Class or Division:

8

Marine pollutant:

NO

Emergency schedule

(Ems):

F-A, S-B

Air (ICAO-IATA):

UN No.:

2735

Name and Description:

AMINES, LIQUID,   CORROSIVE, N.O.S.

(Trioctyl   amine)

Labelling:

8

UN Packing Group:

III

Class or Division:

8

Environment Hazards:

NO

Note:

The above regulatory   prescriptions are those valid on the date of

publication of this   SDS.

                                                                              

Section 15. Regulatory Information

INVENTORY STATUS

Inventory

Status


United States (TSCA)

Canada (DSL)

Europe (EINECS /   ELINCS)

Australia (AICS)

Japan (METI)

South Korea (KECI)

China (IECSC)

New Zealand (NZIoC)

Philippines (PICCS)

Y

Y

Y

Y

Y

Y

Y

Y

Y

 

Y = All ingredients are on the inventory.

E = All ingredients are on the inventory or exempt from listing.

P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are on the inventory or exempt from listing.

N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing.

NOTE The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the SDS.The user’s attention is drawn to the possible existence of additional provisions which complete these regulations.Refer to all applicable national, international and local regulations or provisions.

                                                                                       

Section 16. Other Information

FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.

H315: Causes skin   irritation.

H319: Causes serious   eye irritation.

H335: May cause   respiratory irritation.

H413: May cause long   lasting harmful effects to aquatic life. [Korea Occupational Safety   &Health Agency, June 2010.]

 

FULL TEXT OF P-STATEMENTS REFERRED TO UNDER SECTIONS 2.

P261: Avoid breathing   dust/fume/gas/mist/vapours/spray.

P264: Wash hands and   face thoroughly after handling.

P271: Use only   outdoors or in a well-ventilated area.

P273: Avoid release to   the environment.

P280: Wear protective   gloves/protective clothing/eye protection/face protection (refer to Section 8

of this Safety Data   Sheet).

P302 + P352: IF ON   SKIN: Wash with plenty of soap and water.

P304 + P340: IF   INHALED: Remove victim to fresh air and keep at rest in a position   comfortable

for breathing.

P305 + P351 + P338: IF   IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if   present and easy to do. Continue rinsing.

P332 + P313: If skin   irritation occurs: Get medical advice/attention.

P370 + P378: In case   of fire: Use water spray, multi-purpose powders, foam or Carbon Dioxide

(CO2) for extinction.   Note: Do not use a water jet since it may cause the fire to spread.

P312: Call a POISON   CENTER or doctor/physician if you feel unwell.

P403 + P235: Store in   a well-ventilated place. Keep cool.

P405: Store locked up.

P501: Dispose of   contents / container in accordance with local regulations.

 

FULL TEXT OF R PHRASES REFERRED TO UNDER SECTIONS 2 AND 3.

R phrases:

R36/37/38: Irritating   to eyes, respiratory system and skin.

R53: May cause   long-term adverse effects in the aquatic environment.

 

REASONS FOR REVISIONS:

Nil

Date Prepared

2014-06-20

Prepared By .

LUOYANG MINE FRIEND TRADING CO.,LTD

Date Superseded

2011-06-15

The information herein   is given in good faith but no warranty is expressed nor implied.

 

To the best of the manufacturer’s knowledge, the information contained herein is accurate. However, neither the manufacturer, nor any of its affiliate, make any representative or warranties (expressed or implied), nor assumes any liability including liability for any direct, incidental, consequential, or the damages) with respect to the accuracy or completeness of the information contained herein. Such information may be (without limitation) invalid if the specification material is used in combination with another, in a particular process, or under unusual conditions. Determination of suitability of any material for any given purpose is the sole responsibility of the user who assumes all risk and responsibility therefore. All material may present unknown hazards and should be used with appropriate caution. The manufacturer cannot and does not guarantee that the hazards described herein are the only ones that exist.