洛阳矿友贸易有限公司
MSDS: | KY005-EN |
DATE: | 6/20/2014 |
LUOYANG MINE FRIEND TRADING CO., LTD
MATERIAL SAFETY DATE SHEET
Section 1. Chemical Product and Company Identification
Chemical Name | Trioctyl amine |
Product name | Trioctyl amine; TOA |
Material Uses | It’s mainly used to synthesis of cationic and amphoteric surfactants etc, which are used as fiber detergents, fabric-softeninig agents. anticorrosice agents, flotation agents of ore and emulsion agents of bitumen etc. |
Manufacturer | LUOYANG MINE FRIEND TRADING CO.,LTD Room513, Building1,World Trade Center,258 Kaiyuan Avenue,Luolong District,Luoyang,China TEL:0086-379-61109972 FAX:0086-379-61109952 |
Section 2. Hazard identification
GHS HAZARD CLASSIFICATION:
PHYSICAL: | No classification. |
HEALTH: | Skin corrosion/irritation: Category 2 – H315: Causes skin irritation. Serious eye damage/eye irritation: Category 2 – H319: Causes serious eye irritation. STOT SE. Category 3- H335: May cause respiratory irritation. |
ENVIRONMENTAL: | Chronic hazards to the aquatic environment: Category 4 – H413: May cause long lasting harmful effects to aquatic life. [Korea Occupational Safety & Health Agency, June 2010.] |
GHS LABEL ELEMENTS:
PICTOGRAM: | |
SIGNAL WORD: | Warning |
HAZARD STATEMENTS:
| H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H413: May cause long lasting harmful effects to aquatic life. [Korea Occupational Safety & Health Agency, June 2010.]
|
PRECAUTIONARY STATEMENTS:
| PREVENTION: P261: Avoid breathing dust/fume/gas/mist/vapors/spray. P264: Wash hands and face thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection (refer to Section 8 of this Safety Data Sheet). RESPONSE: P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313: If skin irritation occurs: Get medical advice/attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. STORAGE: P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. DISPOSAL: P501: Dispose of contents / container in accordance with local regulations. |
EC REGULATIONS:
CLASSIFICATION [REGULATION (EC) No. 1272/2008]:
Skin corrosion/irritation: Category 2 | H315: Causes skin irritation. |
Serious eye damage/eye irritation: Category 2 | H319: Causes serious eye irritation. |
STOT SE: Category 3 | H335: May cause respiratory irritation. |
Chronic hazards to the aquatic environment: Category 3 | H413: May cause long lasting harmful effects to aquatic life. |
CLASSIFICATION [REGULATION 67/548/EEC; 1999/45/EC]:
– IRRITANT (Xi) | R36/37/38: Irritating to eyes, respiratory system and skin. |
– DANGEROUS FOR THE ENVIRONMENT (N) | R53: May cause long-term adverse effects in the aquatic environment. |
Section 3. Composition, Information on Ingredients
COMPONENTS | CAS No. EINECS No. | Self / EC Classification | Classification Regulation (EC) No. 1272/2008 | WT% |
Trioctyl amine | 1116-76-3 214-242-1 | Xi; R36/37/38, -N;R53
| H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H413: May cause long lasting harmful effects to aquatic life.
| ≥95.0
|
Water | 7732-18-5 231-791-2 | —— | —— | ≤0.5 |
For the full text of the R-Phrases mentioned in this section, see Section 16.
For the full text of the H-Statements mentioned in this section, see Section 16.
Section 4. First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively. For methemoglobinemia,administer oxygen alone or with Methylene blue depending on the methemoglobinemia concentration in the blood.
Antidote: Methylene blue, alone or in combination with oxygen is indicated as a treatment in nitrite induced methemoglobinemia.
Section 5. Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Vapors may form an explosive mixture with air. Containers may explode when heated.Combustible material; may burn but does not ignite readily. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Flash Point: > 112 deg C (> 233.60 deg F)
Autoignition Temperature: 315 deg C ( 599.00 deg F)
Explosion Limits, Lower: Not available. Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0
incompatible substances.
Section 8. Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name | ACGIH | NIOSH | OSHA - Final PELs |
Trioctyl amine | none listed | none listed | none listed |
OSHA Vacated PELs: Trioctyl amine: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9. Physical and Chemical Properties
Physical State: Liquid
Appearance: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 12.1
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 365 - 367 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: insoluble
Specific Gravity/Density:.8090g/cm3
Molecular Formula: C27H57N
Molecular Weight: 350.65
Flash Point: > 112 deg C (> 233.60 deg F)
Autoignition Temperature: 315 deg C ( 599.00 deg F)
Explosion Limits, Lower: Not available. Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0
Section 10. Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials: Oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
Section 11. Toxicological Information
Potential Health Effects
Eye: Causes eye irritation. May cause chemical conjunctivitis.
Skin: Causes skin irritation. May cause severe irritation and possible burns.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause
liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and
death. May cause central nervous system depression.
Inhalation: Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis,
convulsions, tachycardia, dyspnea (labored breathing), and death. May cause liver and kidney
damage. May cause cardiac abnormalities. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic: May cause liver and kidney damage. May cause methemoglobinemia, which is
characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate,
unconsciousness and possible death. Effects may be delayed.
RTECS#: No information found.
CAS# ： 1116-76-3
LD50/LC50: Not available.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Neurotoxicity: No information available.
Mutagenicity: No information found.
Other Studies: No data available.
Section 12. Ecological Information
No information available.
Section 13. Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14. Transport Information
Land - Rail / Road | UN No.: | 2735 |
(RID / ADR): | Name and Description: | AMINES, LIQUID, CORROSIVE, N.O.S. (Trioctyl / Decyl amine) |
Labelling: | 8 | |
UN Packing Group: | III | |
Class or Division: | 8 | |
Environment Hazards: | NO | |
Sea (IMO / IMDG):
| UN No.: | 2735 |
Name and Description: | AMINES, LIQUID, CORROSIVE, N.O.S. (Trioctyl amine) | |
Labeling: | 8 | |
UN Packing Group: | III | |
Class or Division: | 8 | |
Marine pollutant: | NO | |
Emergency schedule (Ems): | F-A, S-B | |
Air (ICAO-IATA): | UN No.: | 2735 |
Name and Description: | AMINES, LIQUID, CORROSIVE, N.O.S. (Trioctyl amine) | |
Labelling: | 8 | |
UN Packing Group: | III | |
Class or Division: | 8 | |
Environment Hazards: | NO | |
Note: | The above regulatory prescriptions are those valid on the date of publication of this SDS. | |
Section 15. Regulatory Information
INVENTORY STATUS | Inventory | Status |
United States (TSCA) Canada (DSL) Europe (EINECS / ELINCS) Australia (AICS) Japan (METI) South Korea (KECI) China (IECSC) New Zealand (NZIoC) Philippines (PICCS) | Y Y Y Y Y Y Y Y Y |
Y = All ingredients are on the inventory.
E = All ingredients are on the inventory or exempt from listing.
P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are on the inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing.
NOTE The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the SDS.The user’s attention is drawn to the possible existence of additional provisions which complete these regulations.Refer to all applicable national, international and local regulations or provisions.
Section 16. Other Information
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H413: May cause long lasting harmful effects to aquatic life. [Korea Occupational Safety &Health Agency, June 2010.] |
FULL TEXT OF P-STATEMENTS REFERRED TO UNDER SECTIONS 2.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash hands and face thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection (refer to Section 8 of this Safety Data Sheet). P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313: If skin irritation occurs: Get medical advice/attention. P370 + P378: In case of fire: Use water spray, multi-purpose powders, foam or Carbon Dioxide (CO2) for extinction. Note: Do not use a water jet since it may cause the fire to spread. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents / container in accordance with local regulations. |
FULL TEXT OF R PHRASES REFERRED TO UNDER SECTIONS 2 AND 3.
R phrases: | R36/37/38: Irritating to eyes, respiratory system and skin. R53: May cause long-term adverse effects in the aquatic environment. |
REASONS FOR REVISIONS:
Nil
Date Prepared 2014-06-20 | Prepared By . LUOYANG MINE FRIEND TRADING CO.,LTD |
Date Superseded 2011-06-15 | The information herein is given in good faith but no warranty is expressed nor implied. |
To the best of the manufacturer’s knowledge, the information contained herein is accurate. However, neither the manufacturer, nor any of its affiliate, make any representative or warranties (expressed or implied), nor assumes any liability including liability for any direct, incidental, consequential, or the damages) with respect to the accuracy or completeness of the information contained herein. Such information may be (without limitation) invalid if the specification material is used in combination with another, in a particular process, or under unusual conditions. Determination of suitability of any material for any given purpose is the sole responsibility of the user who assumes all risk and responsibility therefore. All material may present unknown hazards and should be used with appropriate caution. The manufacturer cannot and does not guarantee that the hazards described herein are the only ones that exist.